"Then the devil took him to the holy city and had him stand on the highest point of the temple. 'If you are the Son of God,' he said, 'throw yourself down. For it is written: "He will command his angels concerning you, and they will lift you up in their hands, so that you will not strike your foot against a stone."' Jesus answered him, 'It is also written: "Do not put the Lord your God to the test."'" NIV translation
For the second test, Jesus went to the temple in Jerusalem. This was a spiritual test in pride as it was an attempt to force God to act. The devil quoted from Psalm 91:11 & 12 but used it out of context. The Psalm speaks of the fact that, if you trust in God, He will not fail to protect you. Jesus answered with the words of Moses again from Deuteronomy 6:16. The Israelites had demanded water from a rock as a sign that God was with them (see Exodus 17). Before they entered the Promised Land, Moses warned them to not test God like they had before.